Abstract
This study was conducted to assess the physicochemical quality of groundwater around municipal solid waste dumpsites in Obio-Akpor Local Government Area. Four objectives guided the research: to assess the physicochemical quality of leachates from municipal solid waste dumpsites, to assess the physicochemical quality of groundwater around municipal solid waste dumpsites, and to assess the concentration of heavy metals (Lead, Arsenic, Cadmium) in groundwater around municipal solid waste dumpsites in Obio Akpor Local Government Area. Groundwater samples were collected from twelve boreholes around two dumpsites at distances of less than 50 meters and 51-300 meters from the dumpsites. Six leachate samples were collected from the drains of both dumpsites. The samples were analyzed for physicochemical parameters, including pH, Electrical Conductivity (EC), Temperature, Turbidity, Total Dissolved Solids (TDS), Total Suspended Solids (TSS), Chloride, Fluoride, Nitrate, Salinity, Dissolved Oxygen (DO), Chemical Oxygen Demand (COD), Biological Oxygen Demand (BOD), Arsenic, Lead, and Cadmium. The physicochemical analysis revealed that all samples had acidic pH levels below the WHO and NSDWQ permissible limit. Parameters such as Temperature, Electrical Conductivity, Turbidity, Nitrate, Fluoride, Chloride, Total Dissolved Solids, and Total Suspended Solids were within WHO guidelines. However, Chemical Oxygen Demand (COD), Biological Oxygen Demand (BOD), Salinity, Fluoride, Dissolved Oxygen (DO), Arsenic, Lead, and Cadmium exceeded the WHO permissible limits, indicating groundwater contamination. Statistical analysis using one-way ANOVA showed significant differences (p < 0.05) in the contamination levels of most parameters across the distances.
References
Akpan, V. E., & Olukanni, D. O. (2020). Hazardous waste management: An African overview. Recycling, 5(3), 15. Barambu, A. U., Maigari, A. U., & Sulaiman, M. B. (2020). Levels of Heavy Metals in a Groundwater around a Municipal Solid Waste Dumpsite in Bauchi, Nigeria: Assessing the Health Impact. Journal ofChemical ofNigeria, http://journals.chemsociety.org.ng/index.php/jcsn/article/view/454 Bukunmi, A., & Achi, C. (2021). ASSESSMENT OF THE IMPACT OF SOLID WASTE DUMP SITE ON SURROUNDING WELLS’ WATER QUALITY: A CASE STUDY OF AGBOWO, IBADAN. Dahiya, V. (2022). Heavy metal toxicity of drinking water: A silent killer. GSC Biological and Pharmaceutical Sciences, 19(1), 020–025. Dave, D. M., & Yang, M. (2022). Lead in drinking water and birth outcomes: A tale of two water treatment plants. Journal of Health Economics, 84, 102644. Ding, Y., Zhao, J., Liu, J.-W., Zhou, J., Cheng, L., Zhao, J., Shao, Z., Iris, Ç., Pan, B., & Li, X. (2021). A review of China’s municipal solid waste (MSW) and comparison with international regions: Management and technologies in treatment and resource utilization. Journal of Cleaner Production, 293, 126144. Dixit, A., Singh, D., & Shukla, S. K. (2024). Assessment of human health risk due to leachate- contaminated soil at the solid waste dumpsite, Kanpur (India). International Journal of Environmental Science and Technology, 21(1), 909–924. https://doi.org/10.1007/s13762- 023-04868-y Ferreira, C. S. S., Adama-Ajonye, O., Ikenna, A. E., & Kalantari, Z. (2023). Groundwater quality in the vicinity of a dumpsite in Lagos metropolis, Nigeria. Geography and Sustainability, 4(4), 379–390. https://doi.org/10.1016/j.geosus.2023.09.005 Grinberga, L., Celms, A., Dzi?cio?, J., G?uchowski, A., Grabuža, D., Gr?nfelde, I., Lauva, D., & Sas, W. (2022). Analysis of the removal of BOD5, COD, and suspended solids in a subsurface flow constructed wetland in Latvia. ACTA SCIENTIARUM POLONORUM - Architectura Budownictwo, 20(4), 21–28. https://doi.org/10.22630/ASPA.2021.20.4.31 Hurra, W. A., & Bhawsar, A. (2021). Assessment of groundwater quality near the solid waste dumping site Bhanpur, Bhopal. Int. J. Appl. Res, 7(8), 314–319. Hussein Farh, H. M., Ben Seghier, M. E. A., Taiwo, R., & Zayed, T. (2023). Analysis and ranking of corrosion causes for water pipelines: A critical review. NPJ Clean Water, 6(1), 65. Kulkarni, S. J. (2016). A review of research and studies on dissolved oxygen and its affecting parameters. International Journal of Research and Review, 3(8), 18–22. Lawal, I. A., Achi, C. G., & Coker, A. O. (2025). Assessment of Refuse Dumpsite Impact on Groundwater Quality: A Case Study from Awotan, Ibadan, Oyo State, Nigeria. Science, Engineering and Technology, 5(1). https://setjournal.com/SET/article/view/161 Mulware, S. J. (2020). Toxicity of Heavy Metals, A. Subject in Review. International Journal of Recent Research in Physics and Chemical Sciences, 6(2), 30–43. Omer, N. H. (2019). Water quality parameters. Water Quality-Science, Assessments and Policy, 18, 1–34. Omorogieva, O. M., Tonjoh, J. A., & Brisibe, O. (2022). Assessments of Heavy Metal Contamination in Groundwater Source from Benin Formation Aquifer in and around Dumpsite Environment, and its Impact on Human Health. Journal of Applied Sciences and Environmental Management, 26(2), 323–334. Parvin, F., & Tareq, S. M. (2021). Impact of landfill leachate contamination on surface and groundwater of Bangladesh: A systematic review and possible public health risks assessment. Applied Water Science, 11(6), 100. https://doi.org/10.1007/s13201-021-01431- 3 Saalidong, B. M., Aram, S. A., Otu, S., & Lartey, P. O. (2022). Examining the dynamics of the relationship between water pH and other water quality parameters in ground and surface water systems. PloS One, 17(1), e0262117. Sabiu, M. (n.d.). ASSESSMENT OF THE EFFECTS OF DUMP SITE ON GROUNDWATER QUALITY IN BARIKIN-SALE, MINNA NORTH-CENTRAL, NIGERIA. Sam-Uroupa, R. E., & Ogbeibu, E. A. (2020). Impact of solid waste dump-sites on groundwater quality in Benin City, Nigeria. African Journal of Health, Safety and Environment, 1(1), 38–63. Ullah, Z., Rashid, A., Ghani, J., Nawab, J., Zeng, X.-C., Shah, M., Alrefaei, A. F., Kamel, M., Aleya, L., & Abdel-Daim, M. M. (2022). Groundwater contamination through potentially harmful metals and its implications in groundwater management. Frontiers in Environmental Science, 10, 1021596. Yadav, S., Bajar, S., Hemraj, Rohilla, R., Chhikara, S. K., & Dhankhar, R. (2023). Assessment of groundwater quality near municipal solid waste landfill by using multivariate statistical technique and GIS: A case study of Bandhwari (Gurugram) landfill site, Haryana, India. Sustainable Water Resources Management, 9(6), 174. https://doi.org/10.1007/s40899-023- 00964-6